UHPLC Column, RP PFP, 1.8um, 100A. 4.6mm ID x 100mm Length. Cogent Brand. 1 EA.

Additional Info:

The 68122‑10P Cogent RP PFP™ UHPLC Column is designed for enhanced selectivity of halogenated, aromatic, and polar compounds, delivering improved resolution where conventional C18 methods may lack specificity.

This stationary phase uses a pentafluorophenyl (PFP) ligand bonded via a four‑carbon linker to high‑purity silica with full double end‑capping, providing multiple interaction mechanisms such as π‑π interactions, dipole interactions, and hydrogen bonding. These combined mechanisms allow for greater selectivity control and improved separation of structurally similar analytes.

This column is well suited as an alternative for USP L43 methods and for new method development requiring different retention behavior than traditional reversed‑phase columns.

100 mm Length – Increased Resolution for Analytical Workflows

The 100 mm length provides a strong balance between resolution and run time, improving separation without the longer cycles of 150 mm or 250 mm columns.

  • Better resolution than 50 mm screening columns

  • Improved separation of closely related compounds

  • Increased peak capacity for complex samples

✅ Use when additional resolving power is needed beyond fast screening methods

Flow Rate & System Requirements (4.6 mm ID, 1.8 µm)

⚠️ Requires UHPLC system capability due to high backpressure

  • Typical flow rate range: ~1.0–2.0 mL/min

  • Optimal starting range: ~1.2–1.5 mL/min

  • Requires stable high‑pressure pumping

  • Compatible with standard analytical detectors

✅ Sample preparation requirement: filter samples using a 0.2 µm syringe filter prior to injection

Why Choose PFP for Selective Separations

Enhanced Retention for Halogenated Compounds

  • Strong interaction with fluorinated and halogenated analytes

  • Improved selectivity compared to C18

Multiple Interaction Mechanisms

  • π‑π interactions for aromatic compounds

  • Dipole and hydrogen bonding interactions

  • Broader selectivity range for method development

Improved Resolution Without Extended Run Time

  • Enables faster methods with maintained or improved separation

  • Ideal for optimizing existing analytical workflows

Cogent RP PFP™ Advantages

Fully End‑Capped Surface

  • Minimizes secondary silanol interactions

  • Improves peak symmetry for polar analytes

High Efficiency (1.8 µm Particles)

  • High plate counts and peak capacity

  • Faster separations vs 3 µm and larger particles

High Purity Silica

  • Consistent performance and reproducibility

  • Reliable method transfer and validation

Typical Applications

  • Halogenated compound analysis

  • Aromatic compound separations

  • Pharmaceutical QA/QC and development

  • LC‑MS and HPLC analytical workflows

  • USP L43 method applications

Important Usage Notes

  • ⚠️ Requires UHPLC system (high pressure capable)

  • Designed for high‑efficiency analytical workflows

  • Higher backpressure than larger particle columns

  • Use 0.2 µm filtration to maintain column performance

 

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